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571.
Multiple biotic and abiotic drivers regulate the balance between CO2 assimilation and release in surface waters. In the present study, we compared in situ measurements of plankton carbon metabolism (primary production and respiration) to calculated air–water CO2 fluxes (based on abiotic parameters) during 1 year (2008) in a hypereutrophic tropical estuary (Recife Harbor, NE Brazil – 08°03′S, 34°52′W) to test the hypothesis that high productivity leads to a net CO2 flux from the atmosphere. The calculated CO2 fluxes through the air–water interface (FCO2) were negative throughout the year (FCO2: –2 to –9 mmol C·m?2·day?1), indicating that Recife Harbor is an atmospheric CO2 sink. Respiration rates of the plankton community ranged from 2 to 45 mmol C·m?2·hr?1. Gross primary production ranged from 0.2 to 281 mmol C·m?2·hr?1, exceeding respiration during most of the year (net autotrophy), except for the end of the wet season, when the water column was net heterotrophic. The present results highlight the importance of including eutrophic tropical shallow estuaries in global air–water CO2 flux studies, in order to better understand their role as a sink of atmospheric CO2.  相似文献   
572.
Several environmental health studies suggest birth weight is associated with outdoor air pollution during gestation. In these studies, exposure assignments are usually based on measurements collected at air quality monitoring stations that do not coincide with health data locations. So, estimated exposures can be misleading if they do not take into account the uncertainty of exposure estimates. In this article we conducted a semi-ecological study to analyze associations between air quality during gestation and birth weight. Air quality during gestation was measured using a biomonitor, as an alternative to traditional air quality monitoring stations data, in order to increase spatial resolution of exposure measurements. To our knowledge this is the first time that the association between air quality and birth weight is studied using biomonitors. To address exposure uncertainty at health locations, we applied geostatistical simulation on biomonitoring data that provided multiple equally probable realizations of biomonitoring data, with reproduction of observed histogram and spatial covariance while matching for conditioning data. Each simulation represented a measure of exposure at each location. The set of simulations provided a measure of exposure uncertainty at each location. To incorporate uncertainty in our analysis we used generalized linear models, fitted simulation outputs and health data on birth weights and assessed statistical significance of exposure parameter using non-parametric bootstrap techniques. We found a positive association between air quality and birth weight. However, this association was not statistically significant. We also found a modest but significant association between air quality and birth weight among babies exposed to gestational tobacco smoke.  相似文献   
573.
Quantification of traffic noise levels in urban areas can be especially useful for environmental and public health policies. A statistical model is proposed here for this quantification in small urban areas. The model is nonlinear and mixed, with two components: a fixed component for traffic noise emission (source effect) and a random component for assessing traffic noise propagation. The proposed model requires only sample data and has been used to estimate basic noise indicators established in European standards. A composite indicator, the Lden indicator, has been computed and used to draw up a noise ranking of urban areas. The proposed approach is applied to the city of Leganés (Spain).  相似文献   
574.
575.
The production of biosolids in three Spanish wastewater treatment plants (WWTPs) has been investigated. Biosolids produced from the treatment of urban wastewater in Spain are usually intended for agricultural use. The reliable production of biosolids mainly depends on both the quantity of suspended solids and the organic load influent to the treatment systems. The quality of the generated biosolids was independent of both the amount of treated water and the treatment process applied, with 20 to 25% dried matter, and 60 to 75%, 7% and 4% of organic matter, N and P, respectively, of the total matter. The biosolids contained ca. 11 to 19 g/kg of total metals in the dry matter, with Fe, Zn, Cu and Mn representing 97% of all of the metals present, and Hg being the minority metal. Such biosolids had the ability to concentrate the organic matter and metals from the wastewater up to 417 and 869 times, respectively, and thus, can be used in agricultural practice.  相似文献   
576.
Recent observations and missions to Mars have provided us with new insight into the past habitability of Mars and its history. At the same time they have raised many questions on the planet evolution. We show that even with the few data available we can propose a scenario for the evolution of the Martian atmosphere in the last three billion years. Our model is obtained with a back integration of the Martian atmosphere, and takes into account the effects of volcanic degassing, which constitutes an input of volatiles, and atmospheric escape into space. We focus on CO2, the predominant Martian atmospheric gas.Volcanic CO2 degassing rates are obtained for different models of numerical model crust production rates [Breuer, D., Spohn, T. 2003. Early plate tectonics versus single-plate tectonics on Mars: Evidence from magnetic field history and crust evolution. J. Geophys. Res. - Planets, 108, E7, 5072, Breuer, D., Spohn, T., 2006. Viscosity of the Martian mantle and its initial temperature: Constraints from crust formation history and the evolution of the magnetic field. Planet. Space Sci. 54 (2006) 153–169; Manga, M., Wenzel, M., Zaranek, S.E., 2006. Mantle Plumes and Long-lived Volcanism on Mars as Result of a Layered Mantle. American Geophysical Union Fall Meeting 2006, Abstract #P31C-0149.] and constrained on observation. By estimating the volatile contents of the lavas, the amount of volatiles released in the atmosphere is estimated for different scenarios. Both non-thermal processes (related to the solar activity) and thermal processes are studied and non-thermal processes are incorporated in our modelling of the escape [Chassefière, E., Leblanc, F., Langlais, B., 2006, The combined effects of escape and magnetic field history at Mars. Planet. Space Sci. Volume 55, Issue 3, Pages 343–357.]. We used measurements from ASPERA and Mars Express and these models to estimate the amount of lost atmosphere.An evolution of the CO2 pressure consistent with its present state is then obtained. A crustal production rate of at least 0.01 km3/year is needed for the atmosphere to be at steady state. Moreover, we show that for most of the scenarios a rapid loss of the primary (and primordial) atmosphere due to atmospheric escape is required in the first 2 Gyr in order to obtain the present-day atmosphere. When CO2 concentration in the mantle is high enough (i.e. more than 800 ppm), our results imply that present-day atmosphere would have a volcanic origin and would have been created between 1 Gyr and 2 Gyr ago even for models with low volcanic activity. If the volcanic activity and the degassing are intense enough, then the atmosphere can even be entirely secondary and as young as 1 Gyr. However, with low activity and low CO2 concentration (less than 600 ppm), the present-day atmosphere is likely to be for the major part primordial.  相似文献   
577.
Modern diatom distribution patterns in the surface sediment of the Ferrol Ría and their relationship to the hydrography and diatom patterns in the water column were studied to determine the hydrographic influence on the record of these biogenic components. Diatom abundance in the water column was assessed for different oceanographic periods and compared with the biosiliceous sedimentary record. Very low abundances were found in the water column during the winter, whereas in spring and summer, diatoms proliferated. Chaetoceros spp. formed the bulk of the water column community during spring and summer, followed by Thalassionema nitzschioides and Rhizosolenia spp. Nitzschia longissima represented a significant portion of the winter assemblage, together with Paralia sulcata and benthic taxa. Leptocylindrus danicus, N. longissima and Skeletonema costatum characterized the autumn campaign, when stratification of the waters occurs, with L. danicus being especially abundant in the outer ría.Seasonal hydrographic and associated productivity patterns govern the abundance and assemblage of the diatoms preserved in surface sediments. Samples located in the inner ría area and its margins exhibited the highest abundances of diatoms, and were primarily dominated by benthic species. The freshwater group, crysophycean cysts and phytoliths were present in the landward stations influenced by river runoff. The middle ría was characterized by P. sulcata and Thalassiosira spp., with minor occurrences of the benthic and freshwater group. Chaetoceros R.S., L. danicus R.S. and T. nitzschioides typified the outer ría, an assemblage that corresponds to nutrient-rich coastal areas of high productivity influenced by oceanic waters, demonstrating the impact of oceanic waters flowing into the embayment due to enhanced tidal mixing through the narrow channel. Therefore, sediment diatom assemblages reflect diatom production patterns in the water column of the Ría. However, we must proceed with caution when interpreting the paleorecord in the inner area due to the high contribution of allochthonous taxa, which is indicative of low water depths. This paper contributes to a better understanding of diatom thanatocoenosis in the Galician Rías, where very few studies of this kind have been done to date.  相似文献   
578.
Stream temperature (Ts) is a key water quality parameter that controls several biological, ecological, and chemical processes in aquatic systems. In forested headwaters, exchanges of energy across air-water-streambed interfaces may influence Ts regimes, especially during storm events as the sources of runoff change over space and time. Analysis of the hysteretic behaviour of Ts during storm events may provide insights into rainfall-runoff responses, but such relationships have not been thoroughly investigated. As such, our objectives were to (a) quantify the variability of stream temperature hysteresis across seasons in different sub-regions and (b) investigate the relationship between the hysteretic response and catchment characteristics. Ts hysteresis during storm events was assessed based on the hysteresis index (HI), which describes the directionality of hysteresis loops, and the temperature response index (TRI), which indicates whether Ts increased or decreased during a storm event. We analysed Ts data from 10 forested headwater reaches in two sub-regions (McGarvey and West Fork Tectah) in Northern California. We also performed a clustering analysis to examine the relationship amongst HI, TRI, topographic metrics, and meteorological characteristics of the study areas. Overall, the hysteretic behaviour of Ts varied across seasons—the greatest HI occurred during spring and summer. Interestingly, in the McGarvey streams the variability in Ts hysteresis co-varied strongly with topographic metrics (i.e., upslope accumulative area, average channel slope, topographic wetness index). Comparatively, in West Fork Tectah the variability of Ts hysteresis co-varied most strongly with meteorological metrics (i.e., antecedent rainfall events, solar radiation, and air temperature). Variables such as the gradient between stream and air temperatures, slope, and wetted width were significant for both sub-regional hysteretic patterns. We posit that the drivers of Ts response during storms are likely dependent on catchment physiographic characteristics. Our study also illustrated the potential utility of stream temperature as a tracer for improving the understanding of hydrologic connectivity and shifts in the dominant runoff contributions to streamflow during storm events.  相似文献   
579.
Mas-Pla  Josep  Brusi  David  Roqué  Carles  Soler  David  Menció  Anna  Costa  Josep M  Zamorano  Manuel  Meredith  Warren 《Hydrogeology Journal》2023,31(3):661-684

The mineral water of Vilajuïga village in Alt Empordà (NE Catalonia, Spain) owes its uniqueness to an emanation of geogenic CO2 that modifies groundwater hydrochemistry to produce a differentiated HCO3–Na- and CO2-rich groundwater among the usual Ca–HCO3 type found in this region. A hydrogeological conceptual model attributes its occurrence to the intersection of two faults: La Valleta and Garriguella-Roses. The former provides a thrust of metamorphic over igneous rocks, formed during the Paleozoic, over a layer of ampelitic shale that, from a hydrogeological perspective, acts as a confining layer. The Garriguella-Roses normal fault, which originated during the Neogene, permits the degassing of geogenic CO2 that is attributed to volcanic activity occurring in the Neogene. Groundwater mixing from the metamorphic and igneous rock units plus the local occurrence of CO2 creates a HCO3–Na water that still holds free-CO2 in solution. Interaction with the gas phase is restricted at the intersection of the two faults. Radiocarbon dating, after correcting for geogenic dead carbon, estimates an age of 8,000 years BP. The low tritium content (0.7 TU) indicates that Vilajuïga water is a mix of “older” groundwater recharged in the metamorphic rocks of the Albera range and “younger” groundwater from the igneous rocks of the Rodes range, over a recharge area of 45 km2 and a maximum elevation of 600 m. Given its origin as rare groundwater in the southern slope of the Eastern Pyrenees, purposeful monitoring is necessary to evaluate the groundwater vulnerability and anticipate impacts from nearby wells and climate-change effects.

  相似文献   
580.
Beach-ridge systems are geomorphological features common in every type of coast and have been widely interpreted as geo-archives of past sea-level, climatic, or tectonic changes. These relict morphological elements are well-known by their facies, architecture, stratigraphy, and evolution. However, the coastal context where beach ridges are formed has never been evaluated. Coastal beach-ridge systems were classified into four main types corresponding to deltaic strandplains, non-deltaic strandplains, spits, and barrier islands. Our study consisted of three scales of analysis: (1) the entire beach-ridge system; (2) beach-ridge sets; and (3) individual beach ridges. Several beach-ridge systems having formed in different types of coastal settings are compared by their present characteristics. Geomorphic data generated from processing and interpreting satellite images combined with previous studies are used to quantify multi-scale attributes of beach-ridge systems. These attributes include the area, length, width, number of sets, number of ridges per set, set rotation, ridge spacing, and ridge elevation. Our findings demonstrate that significant differences define beach-ridge systems including deltaic strandplains, large non-deltaic strandplains, small non-deltaic strandplains, large spits (cuspate forelands), small spits (flying spits, bay-mouth spits and tombolos) and barrier islands. A more comprehensive characterization of the factors controlling beach-ridge variability will improve our ability to recognize the sedimentary record of ancient of these systems. The proposed basic platform can be used to isolated different beach-ridge types and systems to facilitate future process and morphodynamic studies.  相似文献   
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